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雙堿法脫硫  </h1> <div id="mywciow" class="prodA_content"> <img src="/uploads/img1/20210727/60ffd9c2ce29b.jpg" /> <div id="oq2wkig" class="showA"><p>雙堿法是采用鈉基脫硫劑進(jìn)行塔內脫硫，由于鈉基脫硫劑堿性強，吸收二氧化硫后反應產(chǎn)物溶解度大，不會(huì )造成過(guò)飽和結晶，造成結垢堵塞問(wèn)題。另一方面脫硫產(chǎn)物被排入再生池內用氫氧化鈣進(jìn)行還原再生，再生出的鈉基脫硫劑再被打回脫硫塔循環(huán)使用。雙堿法脫硫工藝降低了投資及運行費用，比較適用于中小型鍋爐進(jìn)行脫硫改造。</p><p>雙堿法脫硫副產(chǎn)物為半水合亞硫酸鈣，CaSO3本身為難溶物質(zhì)，可以很輕易的脫硫系統中分離出來(lái)，進(jìn)行堆放處理。但是CaSO3的化學(xué)性質(zhì)不是特別穩定，遇到強酸和高溫都會(huì )分解出SO2，放在空氣里也會(huì )慢慢被氧化成CaSO4，因此根據客戶(hù)要求也常?？紤]將脫硫副產(chǎn)物亞硫酸鈣氧化成性質(zhì)更加穩定的硫酸鈣。</p><p><strong>雙堿法脫硫工藝優(yōu)點(diǎn)</strong></p><p>(1) 技術(shù)成熟，運行經(jīng)濟。雙堿法脫硫，脫硫循環(huán)液基本上是鈉基的水溶液，在循環(huán)過(guò)程中對泵、管道、設備均無(wú)腐蝕與堵塞現象，利于設備的運行與保養。另外雙堿法節能、節水、節省還原劑效果顯著(zhù)，且具有脫硫效率高、可利用率高、可靠性高、投資成本低、運行費用低、占地面積小的特點(diǎn)。</p><p>(2) 工藝，運行費用低。因鈉堿活性極強極高，所以只用很低的液氣比就可達到高效率的脫硫效果；用廉價(jià)的鈣堿再生，鈉堿可以被重復利用，大大降低了運行成本。吸收劑的再生和脫硫副產(chǎn)物的沉淀發(fā)生在脫硫塔以外，避免了系統的堵塞和磨損，提高了運行可靠性，降低了運行費用，同時(shí)系統更加緊湊。</p><p>(3) 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